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Enhanced nanoscale Ge concentration oscillations in Si/SiGe quantum well through controlled segregation

Kevin-P. Gradwohl, Lukas Cvitkovich, Chen-Hsun Lu, Sebastian Koelling, Maximilian Oezkent, Yujia Liu, Dominic Waldhör, Tibor Grasser, Yann-Michel Niquet, M. Albrecht, Carsten Richter, Oussama Moutanabbir and Jens Martin

Discussion or Letter (2025)

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Abstract

The integration of electron spin qubits on Si/SiGe heterostructures requires precise control of valley splitting associated with conduction band degeneracy. This can be achieved by introducing nanoscale oscillating Ge concentration profiles, known as Wiggle Wells. However, the intermixing and segregation of Ge during growth have hindered their realization. We report the growth of Si/SiGe heterostructures with clear nanoscale composition modulation within the quantum well using molecular beam epitaxy. By oscillation of the growth temperature, Ge segregation is suppressed, achieving a Ge concentration modulation of 30%/nm, an order of magnitude higher than prior results. Tight-binding simulations suggest that Wiggle Well heterostructures with sharp compositional transitions significantly enhance valley splitting, yielding average values exceeding 200 μeV, with energy levels well separated from 0 μeV. Hence, Wiggle Wells are a promising approach for Si-based electronic qubits.

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Department: Department of Engineering Physics
Funders: Federal Ministry of Education and Research (BMBF), Leibniz Association, European Union’s Horizon 2020, European Research Council (ERC), NSERC, Canada Research Chairs, Canada Foundation for Innovation, Mitacs, PRIMA Québec, Defence Canada, European Union’s Horizon Europe, U.S. Army Research Office, Air Force Office of Scientific and Research
Grant number: Project 13N15659, Project K124/2018, 871813, 101055379, 101070700, W911NF-22-1-0277, FA9550-23-1-0763
PolyPublie URL: https://publications.polymtl.ca/63275/
Journal Title: Nano Letters (vol. 25, no. 11)
Publisher: American Chemical Society (ACS)
DOI: 10.1021/acs.nanolett.4c05326
Official URL: https://doi.org/10.1021/acs.nanolett.4c05326
Date Deposited: 06 Mar 2025 10:45
Last Modified: 14 Jan 2026 23:51
Cite in APA 7: Gradwohl, K.-P., Cvitkovich, L., Lu, C.-H., Koelling, S., Oezkent, M., Liu, Y., Waldhör, D., Grasser, T., Niquet, Y.-M., Albrecht, M., Richter, C., Moutanabbir, O., & Martin, J. (2025). Enhanced nanoscale Ge concentration oscillations in Si/SiGe quantum well through controlled segregation [Discussion or Letter]. Nano Letters, 25(11), 4204-4210. https://doi.org/10.1021/acs.nanolett.4c05326

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