<  Back to the Polytechnique Montréal portal

Regionalized terrestrial ecotoxicity assessment of copper-based fungicides applied in viticulture

Ivan Viveros Santos, Cécile Bulle, Annie Levasseur, Louise Deschênes

Article (2018)

Open Acess document in PolyPublie and at official publisher
Open Access to the full text of this document
Published Version
Terms of Use: Creative Commons Attribution
Download (420kB)
[img] Open Access to the full text of this document
Spreadsheet - Supplemental Material
Terms of Use: Creative Commons Attribution
Download (4MB)
Show abstract
Hide abstract


Life cycle assessment has been recognized as an important decision-making tool to improve the environmental performance of agricultural systems. Still, there are certain modelling issues related to the assessment of their impacts. The first is linked to the assessment of the metal terrestrial ecotoxicity impact, for which metal speciation in soil is disregarded. In fact, emissions of metals in agricultural systems contribute significantly to the ecotoxic impact, as do copper-based fungicides applied in viticulture to combat downy mildew. Another issue is linked to the ways in which the intrinsic geographical variability of agriculture resulting from the variation of management practices, soil properties, and climate is addressed. The aim of this study is to assess the spatial variability of the terrestrial ecotoxicity impact of copper-based fungicides applied in European vineyards, accounting for both geographical variability in terms of agricultural practice and copper speciation in soil. This first entails the development of regionalized characterization factors (CFs) for the copper used in viticulture and then the application of these CFs to a regionalized life-cycle inventory that considers different management practices, soil properties, and climates in different regions, namely Languedoc-Roussillon (France), Minho (Portugal), Tuscany (Italy), and Galicia (Spain). There are two modelling alternatives to determine metal speciation in terrestrial ecotoxicity: (a) empirical regression models; and (b) WHAM 6.0, the geochemical speciation model applied according to the soil properties of the Harmonized World Soil Database (HWSD). Both approaches were used to compute and compare regionalized CFs with each other and with current IMPACT 2002+ CF. The CFs were then aggregated at different spatial resolutions—global, Europe, country, and wine-growing region—to assess the uncertainty related to spatial variability at the different scales and applied in the regionalized case study. The global CF computed for copper terrestrial ecotoxicity is around 3.5 orders of magnitude lower than the one from IMPACT 2002+, demonstrating the impact of including metal speciation. For both methods, an increase in the spatial resolution of the CFs translated into a decrease in the spatial variability of the CFs. With the exception of the aggregated CF for Portugal (Minho) at the country level, all the aggregated CFs derived from empirical regression models are greater than the ones derived from the method based on WHAM 6.0 within a range of 0.2 to 1.2 orders of magnitude. Furthermore, CFs calculated with empirical regression models exhibited a greater spatial variability with respect to the CFs derived from WHAM 6.0. The ranking of the impact scores of the analyzed scenarios was mainly determined by the amount of copper applied in each wine-growing region. However, finer spatial resolutions led to an impact score with lower uncertainty.

Uncontrolled Keywords

metals; impact assessment; speciation; terrestrial ecotoxicity; pesticides; LCA; regionalization

Subjects: 1500 Environmental engineering > 1500 Environmental engineering
1800 Chemical engineering > 1800 Chemical engineering
4800 Soil science > 4803 Chemistry and mineralogy
Department: Department of Chemical Engineering
Grant number: RDCPJ451916-13
PolyPublie URL: https://publications.polymtl.ca/3576/
Journal Title: Sustainability (vol. 10, no. 7)
Publisher: MDPI
DOI: 10.3390/su10072522
Official URL: https://doi.org/10.3390/su10072522
Date Deposited: 09 Mar 2020 12:22
Last Modified: 19 Nov 2022 06:02
Cite in APA 7: Viveros Santos, I., Bulle, C., Levasseur, A., & Deschênes, L. (2018). Regionalized terrestrial ecotoxicity assessment of copper-based fungicides applied in viticulture. Sustainability, 10(7). https://doi.org/10.3390/su10072522


Total downloads

Downloads per month in the last year

Origin of downloads


Repository Staff Only

View Item View Item