Hamed Nasri Lari, Donya Farhanian, Daria Camilla Boffito
, Gregory Scott Patience, Gregory De Crescenzo, Jamal Chaouki and Jason Robert Tavares
Article (2017)
 Open Access document in PolyPublie |
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Open Access to the full text of this document Accepted Version Terms of Use: Creative Commons Attribution Non-commercial No Derivatives Download (1MB) |
Abstract
During our studies on surface engineering, we photopolymerize syngas onto silicon surfaces. XPS and TOF-SIMS analyses show that the syngas-derived oligomer covalently bonds to free silanol sites. Iron atoms appear in the coating, despite the fact that no iron was (intentionally) added to the system. GC–MS analysis reveals low concentrations of iron pentacarbonyl (IPC) are generated within the carbon monoxide cylinder. Its presence plays a determinant photocatalytic role in the reaction.
Uncontrolled Keywords
Photochemistry, Iron pentacarbonyl, Syngas, Photo-initiated chemical vapor deposition (PICVD), Photopolymerization
| Subjects: | 1800 Chemical engineering > 1800 Chemical engineering |
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| Department: | Department of Chemical Engineering |
| Funders: | CRSNG/NSERC |
| Grant number: | RGPIN 418847-2013 |
| PolyPublie URL: | https://publications.polymtl.ca/2792/ |
| Journal Title: | Catalysis Communications (vol. 100) |
| Publisher: | Elsevier |
| DOI: | 10.1016/j.catcom.2017.06.024 |
| Official URL: | https://doi.org/10.1016/j.catcom.2017.06.024 |
| Date Deposited: | 03 Oct 2017 14:44 |
| Last Modified: | 27 Sep 2024 05:32 |
| Cite in APA 7: | Nasri Lari, H., Farhanian, D., Boffito, D. C., Patience, G. S., De Crescenzo, G., Chaouki, J., & Tavares, J. R. (2017). Shedding light on iron pentacarbonyl photochemistry through a CVD case study. Catalysis Communications, 100, 19-23. https://doi.org/10.1016/j.catcom.2017.06.024 |
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