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On-surface synthesis guided by supramolecular orientation on a Au(111) surface

Frank Palmino, Judicael Jeannoutot, Vincent Luzet, Alain Rochefort and Frédéric Chérioux

Article (2024)

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Abstract

Surface-assisted Ullmann coupling is a verycommon approach to carry out on-surface synthesis. Weinvestigated the deposition of the 1,3,5-tris(4-bromophenyl)-benzene molecule on a Au(111) surface at low temperatures. Weobserved a new supramolecular phase using scanning tunnelingmicroscopy, and we demonstrated that this supramolecularorganization promotes the formation of a well-defined 1D covalentnetwork through thermal annealing.

Subjects: 3100 Physics > 3100 Physics
3100 Physics > 3101 Atomic and molecular studies
Department: Department of Engineering Physics
Funders: French National Agency, Pays deMontbéliard Agglomération
Grant number: NR-20-CE09-0016
PolyPublie URL: https://publications.polymtl.ca/58776/
Journal Title: The Journal of Physical Chemistry C
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.4c04497
Official URL: https://doi.org/10.1021/acs.jpcc.4c04497
Date Deposited: 21 Aug 2024 00:09
Last Modified: 25 Sep 2024 16:51
Cite in APA 7: Palmino, F., Jeannoutot, J., Luzet, V., Rochefort, A., & Chérioux, F. (2024). On-surface synthesis guided by supramolecular orientation on a Au(111) surface. The Journal of Physical Chemistry C, 6 pages. https://doi.org/10.1021/acs.jpcc.4c04497

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